Unfortunately for laundry product manufacturers, sodium salts have the best and the worst characteristics. All sodium salts are highly soluble, hence of a benefit when manufacturers want their products to rapidly dissolve in cold water. Sodium (as the cation) is used in various combinations with anions to form highly soluble salts. Phosphorus is often carried as sodium tripolyphosphate, the sodium part making it highly soluble. Washing soda is sodium carbonate, a highly soluble, yet highly alkaline product.
Secondly, because sodium can be detrimental to plant physiology (affects osmotic pressure in plant cells) and lead to loss of soil structure, the amount of sodium in laundry detergents needs to be limited when the wastewater is to be discharge to vegetation or soil absorption areas. When wastewater is discharged as "ocean outfall' (the dark ages approach to sewage disposal) the sodium concentration is irrelevant, but the loss of phosphorus to the oceans is an obscene waste of a limited, non-renewable resource (environmental vandalism).
When a sodium salt is dissolved in water it ionises to sodium ions (Na+) and the other part as an anion (negative charge) so that the sodium then acts independently of the anion, although influenced by salinity and pH. Take for example sodium tripolyphosphate which is extremely soluble. When dissolved in water it ionises to sodium cations and phosphate anions in equal numbers. The sodium cations act independently of the phosphate anions.
Sodium salts can never be biodegradable because they are inorganic compounds. So the label about biodegradability does not apply to any of the sodium salts in the laundry detergent.
Since the only guide to the 'desirable' upper limit of sodium is based upon loss of plant production, an other term "sodium adsorption ratio" is in common use. This term, when stated simply is a measure of the proportion of sodium relative to beneficial elements calcium and magnesium (the ratio is complex and beyond the scope of this section). See also discussion under the heading "sodium adsorption ratio".
Because sodium is very difficult to remove from wastewater, prevention is better than cure. Consider using products that are low in sodium. Note that concentrated powders have a lower sodium level because of the lower use of "fillers".
It is interesting to note that the products specially formulated for front loaders have high levels of sodium as do many of the generic brands. It can be interpreted from this that these products are more environmentally hazardous than those with very short bars.
If the 'acceptable upper limit' is 20 grams per wash (this must include sodium from the source water), then 55% of the front loading detergents are above this limit and 68% of top loading detergents exceed this value. The greater volume of water from the top loaders give the ability to spread the load of sodium (g/wash) over a greater area. One is limited by the smaller volume of water in front loaders and distributing the sodium load over a large area becomes difficult (mostly likely not done).
The solution is simple. Test out a small section of your garden or lawn to see what happens when you discharge laundry water. Check on the condition of the plants (do they look healthy?) and see what happens to the soil. You can check to see what the soil looks like when you dig up a small section - if it looks to be clumping together - you may have a problem. If the surface looks like its covered with a fine sheet of clays, you again have problems.
Calculation of Sodium per wash
Note: A salt load of 1 tonne per hectare is considered in agricultural enterprises to be level at which the productivity of plants decreases, that is, there is a loss of vegetation because of the stresses introduced into the environment around the plant. While this is a simplistic approach, it is one which provides a rough assessment of the quality of irrigation water. The conversion of 0.4 from sodium to salt is to account for the proportion of sodium in sodium chloride.
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